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Formation of long-lived radicals in radiolysis of oxygen-containing organofluorine compounds

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In the radiolysis of organofluorine compounds containing a phenoxyl substituent, we have observed the formation of radicals, long-lived in the liquid, in the course of gamma irradiation at 77 K. From an analysis of the EPR spectra of the long-lived radicals, it has been shown that the radiolysis forms two types of long-lived radicals: cyclodienyl and alkoxyl. The lifetimes of these radicals depend on the structure of the compound from which they are obtained by radiolysis.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR

    S. R. Allayarov, I. M. Barkalov & Yu. L. Bakhmutov

  2. State Institute of Applied Chemistry, Leningrad

    S. R. Allayarov, I. M. Barkalov & Yu. L. Bakhmutov

Authors
  1. S. R. Allayarov
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  2. I. M. Barkalov
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  3. Yu. L. Bakhmutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1255–1260, June, 1988.

The authors wish to express their appreciation to L. M. Buchachenko for assistance in this work.

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Allayarov, S.R., Barkalov, I.M. & Bakhmutov, Y.L. Formation of long-lived radicals in radiolysis of oxygen-containing organofluorine compounds. Russ Chem Bull 37, 1102–1106 (1988). https://doi.org/10.1007/BF00961909

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  • DOI: https://doi.org/10.1007/BF00961909

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