Conclusions
-
1.
The temperature dependence of the heat capacity of phenyl glycidyl ether in vitreous, crystalline, supercooled liquid and liquid states was studied in an adiabatic vacuum calorimeter in the 14–330‡K range with an error of -0.3 %. The temperature, enthalpy and entropy of fusion, as well the glass transition temperature were determined.
-
2.
The thermodynamic functions H‡(T)-H‡(O), S‡(T), G‡(T)-H‡(O) were calculated for the range of 0–330 K; the zero entropy and the difference between the zero enthalpies of a vitreous and crystalline phenyl glycidyl ether were calculated; the thermodynamic parameters of its formation at a standard pressure and T=298.15 K were calculated.
-
3.
The enthalpy, entropy, and Gibbs energy of the reaction of phenyl glycidyl ether with diphenylcarbodiimide and phenylisocyanate were calculated. It was found that these processes are thermodynamically permissible over the whole temperature range studied and have an upper limiting temperature.
Similar content being viewed by others
Literature cited
V. A. Pankratov, Ts. M. Frenkel', and A. M. Fainleib, Usp. Khim.,52, 1018 (1983).
V. A. Pankratov, Ts. M. Frenkel', A. M. Fainleib, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 474 (1983).
N. Kinjo and S. Numarata, J. Appl. Polym. Sci.,28, 1729 (1983).
Ts. M. Frenkel', V. A. Pankratov, L. I. Komarova, et al., Vysokomol. Soed.,28A, 172 (1986).
A. K. Bonetskaya, M. A. Kravchenko, and Ts. M. Frenkel', Summaries of Lectures at the 4th All-Union Conference on Thermodynamics of Organic Compounds [in Russian], Kuibishev (1985), p. 30.
V. P. Kuznetsova, E. A. Miroshnichenko, A. N. Zelenetskii, et al., Dokl. Akad. Nauk SSSR,226, 1109 (1976).
B. V. Lebedev, T. A. Bykova, E. G. Kiparisova, et al., Zh. Obshch. Khim.,54, 417 (1984).
T. A. Bykova, B. V. Lebedev, E. G. Kiparisova, et al., Zh. Obshch. Khim.,55, 2591 (1985).
T. A. Bykova, E. G. Kiparisova, E. N. Tarasov, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1252 (1987).
B. V. Lebedev and V. Ya. Lityagov, Thermodynamics of Organic Compounds [in Russian], Izd-vo Gork. Gos. Univ., Gorkii (1976), p. 89.
S. Alford and M. Dole, J. Am. Chem. Soc.,77, 4774 (1955).
B. V. Lebedev and I. B. Rabinovich, Dokl. Akad. Nauk SSSR,237, 641 (1977).
Yu. A. Aleksandrov, Accurate Cryometry of Organic Compounds [in Russian], Khimiya, Leningrad (1975), p. 16.
V. P. Glushko (ed.), Constants of Compounds. Handbook [in Russian], Nos. 1–6, VINITI (1965–1972).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1232–1237, June, 1988.
Rights and permissions
About this article
Cite this article
Lebedev, B.V., Bykova, T.A., Kiparisova, E.G. et al. Thermodynamics of phenyl glycidyl ether and its reactions with diphenylcarbodiimide and phenyl isocyanate with the formation of iminooxazolidine and oxazolidinone in the 0–330 K range. Russ Chem Bull 37, 1082–1086 (1988). https://doi.org/10.1007/BF00961904
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00961904