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Reaction of dimethyl phosphite and monomethyl phenylphosphonite with 2-methyl-3,4,5-triphenylcyclopentadienone

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In the absence of catalysts, the reaction of dimethyl phosphite and monomethyl phenylphosphonite with 2-methyl-3,4,5-triphenylcyelopentadienone goes with the formation of unconjugatedβ-phosphonoketones, which under the reaction conditions undergo prototropic isomerization to the conjugatedβ-phosphonoketones. In contrast to alcohols, dimethyl phosphite and monomethyl phenylphosphonite when reacted with the tricyclone do not form the products of 1,4-addition to the conjugated C=C-C=O system of the cyclone.

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Authors and Affiliations

  1. A. M. Butlerov Chemical Institute of the V. I. Ul'yanov-Lenin Kazan State University, USSR

    B. A. Arbuzov, A. V. Fuzhenkova & N. I. Galyautdinov

Authors
  1. B. A. Arbuzov
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  2. A. V. Fuzhenkova
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  3. N. I. Galyautdinov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 904–909, April, 1980.

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Arbuzov, B.A., Fuzhenkova, A.V. & Galyautdinov, N.I. Reaction of dimethyl phosphite and monomethyl phenylphosphonite with 2-methyl-3,4,5-triphenylcyclopentadienone. Russ Chem Bull 29, 651–656 (1980). https://doi.org/10.1007/BF00961623

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  • DOI: https://doi.org/10.1007/BF00961623

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