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Asymmetric nonbridge nitrogen

21. 1-alkoxy-2,2-bis(trifluoromethyl)aziridines

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    When treated with excess diazomethane for a long time the O-alkyloximes of hexafluoroacetone form stable triazolines, which on photolysis or thermolysis give the corresponding 1-alkoxy-2,2-bis(trifluoromethyl)-aziridines.

  2. 2.

    Ihe configurattonal stability of the 1-alkoxy-2,2-bis(trifluoromethyl)aziridines is sufficient to permit their separation into the antipodes. The derivatives with an asymmetric center in the substituent on oxygen were separated into the diasteromers by recrystallization.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow

    R. G. Kostyanovskii, A. V. Prosyanik, A. I. Mishchenko, N. L. Zaichenko, I. I. Chervin & V. I. Markov

  2. Chemical-Techno logical Institute, Dnepropetrovsk

    R. G. Kostyanovskii, A. V. Prosyanik, A. I. Mishchenko, N. L. Zaichenko, I. I. Chervin & V. I. Markov

Authors
  1. R. G. Kostyanovskii
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  2. A. V. Prosyanik
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  3. A. I. Mishchenko
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  4. N. L. Zaichenko
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  5. I. I. Chervin
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  6. V. I. Markov
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Additional information

See [1] for Communication 20.

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 882–888, April, 1980.

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Kostyanovskii, R.G., Prosyanik, A.V., Mishchenko, A.I. et al. Asymmetric nonbridge nitrogen. Russ Chem Bull 29, 632–637 (1980). https://doi.org/10.1007/BF00961619

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  • DOI: https://doi.org/10.1007/BF00961619

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