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Transformations of n-hexane and 1-hexene on aluminum, gallium, and indium oxides

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study of the transformations of n-hexane and 1-hexene under pulse conditions disclosed that the oxide Al2O3 has a very weak, while Ga2O3, and especially In2O3, have a strong aromatizing (dehydrogenation) and hydrogenation activity, but these are still inferior to the oxide Cr2O3.

  2. 2.

    The studied oxides of the Group III elements catalyze the migration of the double bond in olefins.

  3. 3.

    The aromatization of hexane on Ga2O3 and In2O3 proceeds by the same mechanism as holds for other oxide catalysts for the aromatization of hydrocarbons.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. G. Bryukhanov, M. I. Rozengart & G. V. Isagulyants

Authors
  1. V. G. Bryukhanov
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  2. M. I. Rozengart
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  3. G. V. Isagulyants
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 861–864, April, 1980.

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Bryukhanov, V.G., Rozengart, M.I. & Isagulyants, G.V. Transformations of n-hexane and 1-hexene on aluminum, gallium, and indium oxides. Russ Chem Bull 29, 613–616 (1980). https://doi.org/10.1007/BF00961614

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  • DOI: https://doi.org/10.1007/BF00961614

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