Skip to main content
SpringerLink
Log in

Oxidation of secondary cycloalkanols by the lead tetraacetate-metal halide system

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Secondary cyclic alcohols with C5-C8 ring size are oxidized by the lead tetraacetate-metal chloride or bromide system in three directions: with ring cleavage and the formation of ω-haloalkanals and without ring cleavage with the formation of the corresponding ketones and also, for C7-C8, 1,4-epoxycycloalkanes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. G. I. Nikishin and N. I. Kapustina, Izv. Akad. Nauk SSSR, Ser. Khim., 1345 (1984).

  2. N. I. Kapustina, A. Yu. Popkov, R. G. Gasanov, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 2327 (1988).

  3. N. I. Kapustina, A. Yu. Popkov, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 2466 (1986).

  4. S. S. Spektor, N. I. Kapustina, E. P. Kaplan, and G. I. Nikishin, Izv. Akad. Nauk SSSR, Ser. Khim., 1140 (1979).

  5. G. C. Levy and G. L. Nelson, Carbon-13 Nuclear Magnetic Resonance for Organic Chemists, Wiley, New York (1972).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    N. I. Kapustina, A. Yu. Popkov & G. I. Nikishin

Authors
  1. N. I. Kapustina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Yu. Popkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. I. Nikishin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2538–2542, November, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kapustina, N.I., Popkov, A.Y. & Nikishin, G.I. Oxidation of secondary cycloalkanols by the lead tetraacetate-metal halide system. Russ Chem Bull 37, 2289–2293 (1988). https://doi.org/10.1007/BF00959880

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00959880

Keywords

Search

Navigation