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Reaction of halogens with copper(II) bis(diethyldithiocarbamate)

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

It was established by EPR spectroscopy that the reaction of halogens with Cu(dtc)2 has redox character in polar and nonpolar solvents. However, the ligand is oxidized in a polar solvent, and new complexes of copper(II), the coordination sphere of which is formed via different combinations of solvent molecules, halide ions, and dtc−, are formed as a result of intraspheral transformations.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    G. M. Larin, G. A. Zvereva, V. V. Minin & Yu. V. Rakitin

Authors
  1. G. M. Larin
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  2. G. A. Zvereva
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  3. V. V. Minin
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  4. Yu. V. Rakitin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2484–2488, November, 1988.

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Larin, G.M., Zvereva, G.A., Minin, V.V. et al. Reaction of halogens with copper(II) bis(diethyldithiocarbamate). Russ Chem Bull 37, 2237–2240 (1988). https://doi.org/10.1007/BF00959869

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  • DOI: https://doi.org/10.1007/BF00959869

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