Abstract
2,2,2-Trinitroethyl ethers of 2,2-dinitroalcohols and some of their derivatives have been obtained for the first time by nitration of oximes of 2,2,2-trinitroethyl ethers of hydroxy ketones and aldehydes with a HNO3-Ac2O mixture, followed by oxidation with H2O2. Starting carbonyl derivatives were prepared by oxidation and hydrolysis of the propargylic and allylic ethers, respectively, of 2,2,2-trinitroethanol followed by further reactions of these compounds.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2797–2802, December, 1991.
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Luk'yanov, O.A., Pokhvisneva, G.V. 2,2,2-Trinitroethyl ethers of 2,2-dinitroalcohols. Russ Chem Bull 40, 2439–2444 (1991). https://doi.org/10.1007/BF00959717
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DOI: https://doi.org/10.1007/BF00959717