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Novel palladium complex-catalyzed reaction of magnesium amides with allylic electrophiles

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A novel method has been described for the efficient formation of nitrogen-carbon bonds via the reaction of magnesium amides with functionalized nitrogen, oxygen, and sulfur-containing allylic derivatives, catalyzed by transition metal complexes. New high (molecular weight) unsaturated tertiary amines have been prepared.

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Authors and Affiliations

  1. Institute of Chemistry, Bashkir Branch of the Academy of Sciences of the USSR, Ufa

    U. M. Dzhemilev, A. G. Ibragimov, D. L. Minsker & R. R. Muslukhov

Authors
  1. U. M. Dzhemilev
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  2. A. G. Ibragimov
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  3. D. L. Minsker
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  4. R. R. Muslukhov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 406–409, February, 1987.

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Dzhemilev, U.M., Ibragimov, A.G., Minsker, D.L. et al. Novel palladium complex-catalyzed reaction of magnesium amides with allylic electrophiles. Russ Chem Bull 36, 365–368 (1987). https://doi.org/10.1007/BF00959383

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  • DOI: https://doi.org/10.1007/BF00959383

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