Conclusions
The reaction of α-alkoxyacroleins with primary amines affords only Schiff bases, αPiperidinocrotonaldehyde reacts with alkylamines, forming a mixture of 1-(alkylamino)-2piperidino-2-butene, 1,2-bis(alkylamino)-butane, and N-formylpiperidine. Their correlation is determined by the reaction conditions and by the structure of the alkylamine.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimieheskaya, No. 2, pp. 361–363, February, 1987.
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Keiko, N.A., Rulev, A.Y., Kalikhman, I.D. et al. Reactions of α-alkoxy and α-piperidino α,β-unsaturated aldehydes with primary amines. Russ Chem Bull 36, 320–322 (1987). https://doi.org/10.1007/BF00959373
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DOI: https://doi.org/10.1007/BF00959373