Skip to main content
SpringerLink
Log in

Ion pairing of organic ion-radicals. Communication 1. Formation of ion pairs of dianion-radicals of dinitromethane in an aqueous medium

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

Using dianion-radicals of dinitromethane, the possibility has been demonstrated for the first time that Li, Na, and K+ form similar ion pairs with Li+, Na+, and K in aqueous media in the layer next to the electrode. The stoichiometric and thermodynamic parameters of ion pairing were determined and it was shown that the processes intensifies with temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. S. G. Mairanovskii, G. G. Kryukova, and O. S. Kozlova, Elektrokhimiya,18, 1542 (1982).

    Google Scholar 

  2. F. M. Rafikov and V. A. Petosyan, Izv. Akad. Nauk SSSR, Ser. Khim., Vol. 31, 2667 (1982).

    Google Scholar 

  3. P. Duben, Chem. Ber.,26, 3003 (1893).

    Google Scholar 

  4. S. G. Mairanovskii, V. A. Petrosyan, V. I. Slovetskii, and A. A. Fainzil'berg, Izv. Akad. Nauk SSSR, Ser. Khim., Vol. 18, 2390 (1969).

    Google Scholar 

  5. M. K. Kalinowski, Chem. Phys. Lett.,7, 55 (1970).

    Google Scholar 

  6. M. K. Kalinowski, Chem. Phys. Lett.,8, 378 (1971).

    Google Scholar 

  7. L. C. Pauling, The Nature of the Chemical Bond and the Structure of Molecules and Crystals, An Introduction to Modern Structural Chemistry, Cornell Univ. Press, Ithaca (1940), Chapter 10.

    Google Scholar 

  8. M. E. Peover and J. D. Davies, J. Electroanalyt. Chem.,6, 46 (1963).

    Google Scholar 

  9. S. G. Mairanovskii, in: Electrosynthesis and Bioelectrochemistry [in Russian], Nauka, Moscow (1975), p. 252.

    Google Scholar 

  10. I. P. Ryvkina, L. N. Nekrasov, V. A. Petrosyan, and V. I. Slovetskii, Dokl. AN SSSR,220, 1339 (1975).

    Google Scholar 

  11. A. F. Baskakova, V. I. Slovetskii, and A. A. Fainzil'berg, Izv. Akad. Nauk SSSR, Ser. Khim., Vol. 19, 1772 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    V. A. Petrosyan & A. L. Dribin

Authors
  1. V. A. Petrosyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. L. Dribin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, pp. 302–306, February, 1987.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Petrosyan, V.A., Dribin, A.L. Ion pairing of organic ion-radicals. Communication 1. Formation of ion pairs of dianion-radicals of dinitromethane in an aqueous medium. Russ Chem Bull 36, 264–268 (1987). https://doi.org/10.1007/BF00959360

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00959360

Keywords

Search

Navigation