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Cyanoacetylene and its derivatives

3. Base-catalyzed autoheterocyclization of cyanoacetylenic carbinols

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Tertiary cyanoacetylenic carbinols in the presence of alkalis undergo autoheterocyclization with the formation of 2,2-dialkyl-4,5-di(cyanomethylidene)oxetanes.

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Author information

Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    Yu. M. Skvortsov, A. G. Mal'kina, B. A. Trofimov, G. A. Kalabin, A. N. Volkov & V. B. Modonov

Authors
  1. Yu. M. Skvortsov
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  2. A. G. Mal'kina
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  3. B. A. Trofimov
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  4. G. A. Kalabin
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  5. A. N. Volkov
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  6. V. B. Modonov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1349–1353, June, 1980.

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Skvortsov, Y.M., Mal'kina, A.G., Trofimov, B.A. et al. Cyanoacetylene and its derivatives. Russ Chem Bull 29, 967–971 (1980). https://doi.org/10.1007/BF00958818

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  • DOI: https://doi.org/10.1007/BF00958818

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