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Mechanism of the inhibition of oxidation reactions by metal complexes

4. Multiple chain termination in the oxidation of styrene by copper bis(salicylal-4-methoxyanilinate)

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summaky

  1. 1.

    Copper bis(salicylal-4-methoxyanilinate) repeatedly terminates styrene oxidation chains by reactions with peroxyl radicals.

  2. 2.

    The rate constants of the termination of oxidation chains by copper bis(salicylalanilinate), stearate, and bis(salicylal-4-methoxyanilinate) have been measured by the method of initiated oxidation.

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Literature cited

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow

    G. A. Kovtun, D. L. Lysenko, V. A. Kaverinskii, A. S. Berenblyum & I. I. Moiseev

  2. Élektrogorsk Branch of the All-Union Scientific-Research Institute of Petroleum Processing, USSR

    G. A. Kovtun, D. L. Lysenko, V. A. Kaverinskii, A. S. Berenblyum & I. I. Moiseev

Authors
  1. G. A. Kovtun
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  2. D. L. Lysenko
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  3. V. A. Kaverinskii
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  4. A. S. Berenblyum
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  5. I. I. Moiseev
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Additional information

For communication 3, see [1].

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1266–1271, June, 1980.

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Kovtun, G.A., Lysenko, D.L., Kaverinskii, V.A. et al. Mechanism of the inhibition of oxidation reactions by metal complexes. Russ Chem Bull 29, 889–893 (1980). https://doi.org/10.1007/BF00958801

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  • DOI: https://doi.org/10.1007/BF00958801

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