Abstract
In a mixed tert-butanol–chlorobenzene (9 : 1 vol) solution, the consumption of oxygen by a styrene oxide–aniline–copper(II) chloride ternary system is studied. For the first time, the formation of free radical particles is detected in copper(II) salt-catalyzed reaction of styrene oxide with the amine.
Similar content being viewed by others
References
Y. Zhang, M. Wang, P. Li, et al., Org. Lett. 14, 2206 (2012).
L. R. Reddy, M. A. Reddy, N. Bhanumathi, et al., Synthesis, No. 6, 831 (2001).
N. Tan, Sh. Yin, Y. Li, et al., J. Organomet. Chem. 696, 1579 (2011).
A. V. Krylov, A. Kh. Mokhammed, V. V. Egorova, E. Ya. Borisova, N. Yu. Borisova, and V. R. Flid, Russ. Chem. Bull. 61, 1128 (2012).
V. M. Solyanikov, L. V. Petrov, and T. I. Drozdova, Neftekhimiya 26, 766 (1986).
L. V. Petrov and V. M. Solyanikov, Pet. Chem. 50, 437 (2010).
L. V. Petrov and V. M. Solyanikov, Russ. J. Phys. Chem. B 10, 764 (2016).
M. G. Spirin, S. B. Brichkin, and L. V. Petrov, Russ. Chem. Bull. 65, 2452 (2016).
L. V. Petrov and V. M. Solyanikov, Dokl. Phys. Chem. 472, 19 (2017).
L. V. Petrov and V. M. Solyanikov, Pet. Chem. 39, 89 (1999).
V. N. Chichagov, V. M. Solyanikov, T. G. Bondarenko, G. A. Tkacheva, A. P. Zhavoronkov, and E. T. Denisov, Neftekhimiya 20, 559 (1980).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.V. Petrov, V.M. Solyanikov, 2018, published in Khimicheskaya Fizika, 2018, Vol. 37, No. 12, pp. 28–32.
Rights and permissions
About this article
Cite this article
Petrov, L.V., Solyanikov, V.M. Copper(II) Chloride-Catalyzed Oxidation of a Styrene Oxide–Aniline Binary System in a Polar Solvent. Russ. J. Phys. Chem. B 12, 1003–1007 (2018). https://doi.org/10.1134/S1990793118060179
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1990793118060179