Summary
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1.
The reaction of bis(triphenylphosphine)-μ-dichlorodichlorodipalladium(II) with hydrogen in aniline and toluidines is autocatalytic.
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2.
The induction period of the reaction increases with concentration of the complexes, the pressure of hydrogen, and temperature.
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3.
A product with the composition [(PPh3)3(PPh2)2Pd3Cl]Cl has been obtained by the reaction of bis(triphenylphosphine)-μ-dichlorodichlorodipalladium(II) with hydrogen.
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A. S. Berenblyum, A. G. Knizhnik, S. L. Mund, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 1687 (1979).
A. S. Berenblyum, A. G. Knizhnik, S. L. Mund, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 2711 (1978).
J. Chatt and L. M. Venanzi, J. Chem. Soc., 2445 (1957).
A. S. Berenblyum, L. I. Lakhman, I. I. Moiseev, and E. D. Radchenko, Izv. Akad. Nauk SSSR, Ser. Khim., 2417 (1975).
O. V. Gritsenko, A. A. Bagatur'yants, and I. I. Moiseev, Abstracts of Reports to the Third All-Union Conference on Preparation and Physicochemical Properties of Transition Metal Hydrides [in Russian], Moscow (1978), p. 83.
K. R. Dixon and A. D. Rattray, Inorg. Chem.,17, 1099 (1978).
G. W. Bushell, K. R. Dixon, P. M. Moroncy, A. D. Rattray, and Cheng Van, J. Chem. Soc. Chem. Comm., 709 (1977).
V. I. Nefedov, Ya. V. Salyn, I. I. Moiseev, A. S. Berenblyum, A. G. Knizhnik, S. L. Mund, and A. P. Sadovsky, Inorg. Chim. Acta Lett.,35, L 343 (1979).
A. S. Berenblyum, A. P. Aseeva, L. I. Lakhman, and I. I. Moiseev, Izv. Akad. Nauk SSSR, Ser. Khim., 2163 (1977).
J. Chatt and L. M. Venanzi, J. Chem. Soc., 2351 (1957).
D. M. Adams and P. J. Chandler, J. Chem. Soc., A, 588 (1969).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1227–1231, June, 1980.
The authors thank V. I. Nefedov and Ya. V. Salyn' for investigating the complex [(PPh3)3(PPh2)2Pd3Cl]Cl by x-ray-electron spectroscopy.
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Berenblyum, A.S., Aseeva, A.P., Lakhmann, L.I. et al. Activation of molecular hydrogen by transition-metal complexes. Russ Chem Bull 29, 853–856 (1980). https://doi.org/10.1007/BF00958793
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DOI: https://doi.org/10.1007/BF00958793