Conclusions
We have prepared (2-ferrocenylethyl) (π-cyclopentadienyl) dicarbonyl iron by reaction ofπ-C5H5(CO)2FeNa with 2-ferrocenylethyl p-toluenesulfonate or 2-ferrocenylethyl chloride. We have examined its reactions with triphenylcarbonium tetrafluoroborate, ferricinium tetrafluoroborate, mercury(II) chloride, iodine and triphenylphosphine.
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A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, S. A. Eremin, and O. V. Grigor'eva, Izv. Akad. Nauk SSSR, Ser. Khim.,1974, 2645.
A. N. Nesmeyanov, É. G. Perevalova, L. I. Leont'eva, and O. V. Grigor'eva, Izv. Akad. Nauk SSSR, Ser. Khim.,1976, 1171.
R. C. Kerber and D. J. Ehntholt, J. Am. Chem. Soc.,95, 2927 (1973).
A. Wojcicki and L. J. Dizikes, Seventh International Conference of Organomet. Chem. Abstracts 1C, Venice, Italy (1975).
M. J. Nugent, R. E. Carter, and J. H. Richards, J. Am. Chem. Soc.,91, 6145 (1969).
T. C. Flood and F. J. DiSanti, J. Chem. Soc., Chem. Commun.,1975, 18.
A. N. Nesmeyanov, É. G. Perevalova, and O. A. Nesmeyanova, Dokl. Akad. Nauk SSSR,100, 1099 (1955).
M. Gree and D. J. Westlake, J. Chem. Soc. A,1971, 367.
W. P. Giering and M. Rosenblum, J. Organomet. Chem.,25, C71 (1970).
A. N. Nesmeyanov, L. G. Makarova, and V. N. Vinogradova, Izv. Akad. Nauk SSSR, Ser. Khim.,1971, 1600.
R. A. Stukan, S. P. Gubin, A. N. Nesmeyanov, V. I. Gol'danskii, and E. F. Makarov, Teor. Eksp. Khim.,2, 805 (1966).
R. H. Herber, R. B. King, and G. K. Wertheim. Inorg. Chem.,3, 101 (1964).
M. F. Hawthorne, J. Org. Chem.,21, 363 (1956).
A. N. Nesmeyanov, É. G. Perevalova, L. P. Yur'eva, and K. I. Grandberg, Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk,1962, 1772.
J. C. Thomas, US Patent No. 2849471 (1958); Chem. Abs.,53, 4298 (1959).
K. Schlögl and H. Egger, Monatsh. Chem.,94, 376 (1963).
F. Bonati, S. Cenini, and R. Ugo, J. Chem. Soc.A1967, 932.
M. S. Kharasch and A. L. Fenner, J. Am. Chem. Soc.,54, 674 (1932).
C. R. Hauser, I. K. Lindsay, and D. Ledniser, J. Org. Chem.,23, 358 (1958).
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Translated from Izvestiya Akademii Nauk SSSR, No. 11, pp. 2557–2562, November, 1977.
We thank R. A. Stukan for recording and discussing the Mössbauer spectra.
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Nesmeyanov, A.N., Perevalova, É.G., Leont'eva, L.I. et al. (2-Ferrocenylethyl) (π-cyclopentadienyl) dicarbonyliron. Russ Chem Bull 26, 2368–2372 (1977). https://doi.org/10.1007/BF00958729
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DOI: https://doi.org/10.1007/BF00958729