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Reaction of α-hydroxyiminoacetonitrile oxides with potassium thiocyanate

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Potassium thiocyanate reacts with substituted α-hydroxyiminoacetonitrile oxides in acetic acid to give, unexpectedly, 5-(carbamoyl)imino-Δ2-1,4,2-oxathiazo-lines. The structure of 3-(1-adamantyl)-5-(carbamoyl)imino-Δ2-1,4,2-oxathiazo-line has been confirmed by x-ray diffraction.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. I. Kalinina, O. A. Rakitin, L. F. Chertanova, L. I. Khmel'nitskii & I. K. Moiseev

  2. V. V. Kuibyshev Polytechnic Institute, USSR

    M. I. Kalinina, O. A. Rakitin, L. F. Chertanova, L. I. Khmel'nitskii & I. K. Moiseev

Authors
  1. M. I. Kalinina
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  2. O. A. Rakitin
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  3. L. F. Chertanova
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  4. L. I. Khmel'nitskii
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  5. I. K. Moiseev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 885–889, April, 1991.

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Kalinina, M.I., Rakitin, O.A., Chertanova, L.F. et al. Reaction of α-hydroxyiminoacetonitrile oxides with potassium thiocyanate. Russ Chem Bull 40, 784–788 (1991). https://doi.org/10.1007/BF00958574

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  • DOI: https://doi.org/10.1007/BF00958574

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