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Synthesis and catalytic properties of protonated carbonyl-phosphine palladium complexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A palladium carbonyl-hydride complex is obtained upon reduction of palladium acetate in the presence of triphenylphosphine and dilute perchloric acid in n-butanol.

  2. 2.

    Reduction of palladium acetate in acetone gives tris(triphenylphosphine)monohydridopalladium perchlorate.

  3. 3.

    Both of these complexes are able to catalyze the reduction of nitrobenzene by carbon monoxide.

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Authors and Affiliations

  1. Petroleum Institute, Siberian Branch, Academy of Sciences of the USSR, Kemerovo

    A. I. Min'kov, O. A. Efimov, N. K. Eremenko & E. B. Klimenko

  2. Kemerovo State University, USSR

    A. I. Min'kov, O. A. Efimov, N. K. Eremenko & E. B. Klimenko

Authors
  1. A. I. Min'kov
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  2. O. A. Efimov
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  3. N. K. Eremenko
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  4. E. B. Klimenko
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2076–2080, September, 1987.

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Min'kov, A.I., Efimov, O.A., Eremenko, N.K. et al. Synthesis and catalytic properties of protonated carbonyl-phosphine palladium complexes. Russ Chem Bull 36, 1926–1930 (1987). https://doi.org/10.1007/BF00958348

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  • DOI: https://doi.org/10.1007/BF00958348

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