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Polysulfonylethenes. 5. The reactions of tris(organosulfonyl)chloroethenes with amines and thiols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    We have found that, in the process of nucleophilic substitution of vinyls with ionic and nonionic nucleophiles, the reactivity of tris(organosulfonyl)chloroethenes is considerably greater than that for tetrakis(organosulfonyl)ethenes, and, particularly, for 1,2-di(organosulfonyl)-1,2-dichloroethenes.

  2. 2.

    We have discovered multiple reaction pathways for substitution in tris(organo-sulfonyl) chloroethene, combined with the presence in the molecule of two other nucleophiles (RSO2, Cl). We have demonstrated that, under weak nucleophilic conditions, substitution of the RSO2-group is preferred.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    N. E. Dontsova, V. P. Sergeeva, E. N. Prilezhaeva & V. S. Bogdanov

Authors
  1. N. E. Dontsova
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  2. V. P. Sergeeva
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  3. E. N. Prilezhaeva
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  4. V. S. Bogdanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 649–653, March 1989.

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Dontsova, N.E., Sergeeva, V.P., Prilezhaeva, E.N. et al. Polysulfonylethenes. 5. The reactions of tris(organosulfonyl)chloroethenes with amines and thiols. Russ Chem Bull 38, 575–578 (1989). https://doi.org/10.1007/BF00958051

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  • DOI: https://doi.org/10.1007/BF00958051

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