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Cycloaddition and chlorotropic transformations in reactions of dichloromethylenetrifluoroacetamide with phosphites

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Abstract

Reactions of dichlormethylenetrifluoroacetamide with triphenyl phosphite, diethylchlorophosphite (o-phenylene)diethylamidophosphite, (o-phenylene)chlorphosphite, and 2-fluoro-3-isopropyl-5-tert-butyl-1,3,2-oxazaphospholine proceeded as cheletropic [4+1]-cycloaddition. The formed λ5-1,4,2-oxazaphospholines underwent 1,3-migration of the chlorine atom in C=N–C cyclic triad.

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Authors and Affiliations

  1. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02094, Ukraine

    N. V. Kolotilo & P. P. Onys’ko

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  1. N. V. Kolotilo
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  2. P. P. Onys’ko
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Correspondence to P. P. Onys’ko.

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Original Russian Text © N.V. Kolotilo, P.P. Onys’ko, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 3, pp. 391–395.

To the 100th Anniversary of A.N. Pudovik

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Kolotilo, N.V., Onys’ko, P.P. Cycloaddition and chlorotropic transformations in reactions of dichloromethylenetrifluoroacetamide with phosphites. Russ J Gen Chem 86, 534–538 (2016). https://doi.org/10.1134/S1070363216030075

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  • DOI: https://doi.org/10.1134/S1070363216030075

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