Abstract
The allyl Mn(II) organic compounds R1CH=C(R2)CH2MnCl (R1=H, Me; R2=H, Me, Bu), obtained in situ from Grignard reagents and Li2MnCl4, react with esters of 4-bromocrotonic, (2-bromobutylidene)-, (4-bromo-2-butenylidene)-, (2-bromoisobutylidene) malonic, and (2-bromoheptylidene)cyanoacetic acids in THF at −78 to +20‡C to give derivatives of substituted cyclopropanecarboxylic or cyclopropane-1, 1-dicarboxylic acids. These derivatives contain a fragment of the allyl type. When ethers of 2-(bromomethyl)acrylic, 4-bromo-2-methyl-, and 4-bromo-3-methyl-2-butenoic acids are used, cross-combination products result.
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For previous communication, see [1].
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 656–663, March, 1991.
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Kasatkin, A.N., Tsypyshev, O.Y., Romanova, T.Y. et al. σ-Complexes of transition metals in organic synthesis. 9. Reactions of allyl organomanganese compounds with γ-bromine derivatives of esters of α, Β-unsaturated carboxylic acids. Russ Chem Bull 40, 573–580 (1991). https://doi.org/10.1007/BF00957998
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DOI: https://doi.org/10.1007/BF00957998