Skip to main content
SpringerLink
Log in

Thermal polymerization of difurfurylideneacetone: X-ray structural and calorimetric studies

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A calorimetric study has been made of the susceptibility of difurfurylideneacetone (DIFA) and its oxidized product to thermal polymerization. It has been established that the oxidation process takes place only on the surface of the crystals. An x-ray structural study of DIFA crystals has shown that solid-phase thermal polymerization takes place in the crystal matrix through one of the two ethylenic bonds of the molecule under conditions of topochemical control.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. Yu. M. Mamatov, Furan Resins (Production and Application) [in Russian], ONTITéI mikrobioprom, Moscow (1974), pp. 37–42.

    Google Scholar 

  2. Furan Resins and Materials (Catalog), Otd. NIITéKhIM, Cherkassy (1975), pp. 5–7.

  3. I. V. Kamenskii and M. V. Ungursan, Plast. Massy, No. 8, 17 (1960).

    Google Scholar 

  4. V. I. Andrianov, Z. Sh. Safina, and B. L. Tarnopol'skii, Programs “Rentgen-75” [in Russian], OIKhF, Chernogolovka (1975).

    Google Scholar 

  5. I. M. Barkalov and D. P. Kiryukhin, Vysokomol. Soedin., Ser. A,22, No. 4, 723 (1980).

    Google Scholar 

  6. A. N. Chekhlov, Kristallografiya,26, No. 3, 596 (1981).

    Google Scholar 

  7. H. A. Bent, Chem. Rev.,61, No. 3, 275 (1961).

    Google Scholar 

  8. G. M. J. Schmidt, Pure Appl. Chem.,27, No. 6, 647 (1971).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Branch of the N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka

    Z. G. Aliev, L. O. Atovmyan, M. R. Muidinov, G. D. Varlamov & Sh. K. Madaliev

Authors
  1. Z. G. Aliev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. O. Atovmyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. R. Muidinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. D. Varlamov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Sh. K. Madaliev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 606–610, March, 1991.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Aliev, Z.G., Atovmyan, L.O., Muidinov, M.R. et al. Thermal polymerization of difurfurylideneacetone: X-ray structural and calorimetric studies. Russ Chem Bull 40, 525–529 (1991). https://doi.org/10.1007/BF00957988

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957988

Keywords

Search

Navigation