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Synthesis, Properties, and Thermal Transformation of Organomagnesiumoxaneyttroxanealumoxanes

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Abstract—This paper presents a study of organomagnesiumoxaneyttroxanealumoxane oligomers soluble in organic solvents and exhibiting fiber-forming properties. We describe processes underlying the formation of modified alumina structures as a result of the thermal transformation of organoelement precursors into ceramic phases. The physicochemical properties of the organomagnesiumoxaneyttroxanealumoxanes and ceramic samples prepared from them have been studied by nuclear magnetic resonance, IR spectroscopy, scanning electron microscopy, thermogravimetric analysis, X-ray diffraction, and elemental analysis. Polymer fibers have been produced by melt-spinning the fiber-forming organomagnesiumoxaneyttroxanealumoxanes.

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 17-03-00331 A) and the Russian Federation President’s Grants Council (grant no. MK-39.2019.3).

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Authors and Affiliations

  1. State Research Institute for Chemistry and Technology of Organoelement Compounds, sh. Entuziastov 38, 105118, Moscow, Russia

    G. I. Shcherbakova, P. A. Storozhenko, E. A. Novokovskaya, N. S. Krivtsova, N. B. Kutinova, T. L. Apukhtina & M. S. Varfolomeev

  2. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, Leninskii pr. 49, 119991, Moscow, Russia

    A. A. Ashmarin

Authors
  1. G. I. Shcherbakova
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  2. P. A. Storozhenko
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  4. N. S. Krivtsova
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  5. N. B. Kutinova
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  6. T. L. Apukhtina
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  7. M. S. Varfolomeev
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  8. A. A. Ashmarin
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Correspondence to G. I. Shcherbakova or A. A. Ashmarin.

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Shcherbakova, G.I., Storozhenko, P.A., Novokovskaya, E.A. et al. Synthesis, Properties, and Thermal Transformation of Organomagnesiumoxaneyttroxanealumoxanes. Inorg Mater 55, 1068–1078 (2019). https://doi.org/10.1134/S0020168519100133

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  • DOI: https://doi.org/10.1134/S0020168519100133

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