Abstract
Infrared difference spectroscopy has been used to study the association of p-nitrophenol (NP) with butyl acetate (BA) in CCl4 and in undiluted BA. It has been shown that in CCl4, an associate is formed, [NP·BA] ·BA (Ia), in which one molecule of BA is linked to the NP by a hydrogen bond, and the second BA molecule is linked to the H-complex NP·BA by outer-sphere (dipole-dipole) interaction. In undiluted BA with low concentrations of NP, (Ia) is formed; with high concentrations of NP, an associate [(NP)2BA] ·mBA is formed, in which two molecules of NP are bonded successively to each other and with a BA molecule; and the number of outer-sphere BA molecules may depend on the concentration of free BA molecules in the solutions.
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Literature cited
M. D. Goesten and L. J. Shaad, Hydrogen Bonding, Marcel Dekker, New York (1974).
S. Sriraman and V. Shanmugasundaram, Bull. Chem. Soc. Jpn.,39, No. 5, 1070 (1966).
T. Gramstad and E. D. Becker, J. Mol. Struct.,5, No. 4, 253 (1970).
E. I. Matrosov, in: Chemistry and Application of Organophosphorus Compounds [in Russian], M. I. Kabachnik, ed., Nauka, Leningrad (1987), pp. 132–136.
Yu. V. Karyakin and I. I. Angelov, Pure Chemical Reagents [in Russian], GNTI Khim. Lit., Moscow (1955), p. 30.
H. Fritzshe, Spectrochim. Acta,21, No. 4, 799 (1965).
B. V. Rassadin and A. V. Iogansen, Zh. Prikl. Spektrosk.,6, No. 6, 801 (1967).
I. S. Perelygin and T. F. Akhunov, Zh. Prikl. Spektrosk.,18, No. 4, 696 (1973).
S. E. Odinokov, A. A. Mashkovskii, arid Z. A. Tarankova, Zh. Prikl. Spektrosk.,37, No. 2, 284 (1982).
V. M. Bilobrov and V. I. Shurpach, Ukr. Khim. Zh.,49, No. 5, 489 (1983).
E. S. Stoyanov and L. V. Lastovka, Zh. Neorg. Khim.,26, No. 3, 744 (1981).
E. S. Stayanov, in: Theory and Practice of Extraction Methods [in Russian], I. P. Alimarin and V. V. Bagreev, eds., Nauka, Moscow (1985), p. 69.
J. Laane and W. Kiefer, Appl. Spectrosc.,35, No. 3, 267 (1981).
V. M. Bilobrov and V. I. Shurpach, Zh. Obshch. Khim.,52, No. 4, 735 (1982).
V. M. Biblobrov and V. I. Shurpach, Ukr. Khim. Zh.,48, No. 10, 1037 (1982).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 593–599, March, 1991.
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Smol'skaya, E.L., Stoyanov, E.S. & Egutkin, P.L. Intermolecular interactions of p-nitrophenol with butyl acetate, according to IR spectroscopic data. Russ Chem Bull 40, 514–520 (1991). https://doi.org/10.1007/BF00957986
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DOI: https://doi.org/10.1007/BF00957986