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Splitting of perfluorinated tertiary cyclic amines by the action of SbF5

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

It was shown that perfluorinated tertiary cyclic amines are dealkylated by the action of SbF5 with the formation of cyclic azomethines. The presence of a perfluoroalkyl substitutent in the α-position to the nitrogen atom in the amine molecule considerably decreases its stability to the action of antimony pentafluoride.

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Literature cited

  1. V. A. Petrov, G. G. Belen'kii, and L. S. German, Izv. Akad. Nauk SSSR, Ser. Khim., No. 8, 1934 (1985).

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  2. V. A. Petrov, V. K. Kunanets, G. G. Belen'kii, et al., 2nd Soviet-West German Symposium on Fluorine Chemistry [in English], Novosibirsk (1988), p. 57.

  3. V. A. Petrov, V. K. Kunanets, K. N. Makarov, and L. S. German, Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 646 (1989).

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. A. Petrov, V. K. Grinevskaya, E. I. Mysov, K. N. Makarov, M. V. Galakhov & L. S. German

Authors
  1. V. A. Petrov
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  2. V. K. Grinevskaya
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  3. E. I. Mysov
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  4. K. N. Makarov
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  5. M. V. Galakhov
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  6. L. S. German
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1616–1619, July, 1990.

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Petrov, V.A., Grinevskaya, V.K., Mysov, E.I. et al. Splitting of perfluorinated tertiary cyclic amines by the action of SbF5 . Russ Chem Bull 39, 1465–1468 (1990). https://doi.org/10.1007/BF00957861

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  • DOI: https://doi.org/10.1007/BF00957861

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