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Electrochemical synthesis of functionally substituted sulfides

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

A method of synthesis of functionally substituted sulfides by cathode electrolysis of thiols on platinum or carbon glass electrodes in the presence of organyl halides was developed. The method of the rotating disk electrode with ring showed that this process passes through the intermediate formation of a thiolate anion on the cathode, and its reaction with the organyl halide results in a high yield of sulfides.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. E. Niyazymbetov, V. A. Petrosyan, L. D. Konyushkin & V. P. Litvinov

Authors
  1. M. E. Niyazymbetov
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  2. V. A. Petrosyan
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  3. L. D. Konyushkin
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  4. V. P. Litvinov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1605–1609, July, 1990.

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Niyazymbetov, M.E., Petrosyan, V.A., Konyushkin, L.D. et al. Electrochemical synthesis of functionally substituted sulfides. Russ Chem Bull 39, 1454–1457 (1990). https://doi.org/10.1007/BF00957858

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  • DOI: https://doi.org/10.1007/BF00957858

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