Abstract
The synthesis and liquid-crystalline properties of 4-(heptyloxy)-N-(aryl)benzaldimin-2-ols have been described. The compounds obtained have smectic and nematic mesomorphism. Alternation of the bleaching temperatures (Tbl) with variation of the length of the alkyl radical in the N-aryl fragment has been noted. The dependence of Tbl on the contribution of the substituent to the polarizability of the molecule γ2 is expressed by the equation Tbl=9.7+1.7γ2.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1997–2001, September, 1989.
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Galyametdinov, Y.G., Ivanova, G.I. Synthesis and liquid-crystalline properties of 4-(heptyloxy)-n-(aryl)benzaldimin-2-ols. Russ Chem Bull 38, 1835–1839 (1989). https://doi.org/10.1007/BF00957772
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DOI: https://doi.org/10.1007/BF00957772