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Reactions of 3,3-dicyano-2-ferrocenylallyl(cyclopentadienyl)dicarbonyliron with electrophilic and nucleophilic reagents

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The σ-allyl complex Cp (CO)2FeCH2C(Fc)=C (CN)2 reacts with iodine to give products resulting from cleavage to the Fe-C σ-bond by iodine, and also an addition product of iodine to the double bond of the allyl ligand, but is stable with respect to hydrogen chloride, sulfur trioxide, and tetracyanoethylene.

  2. 2.

    The C-Fe σ-bond in Cp(CO)2FeCH2C (Fc)=C(CN)2 is easily cleaved by nucleophilic reagents (LiAlH4 and LiC5H4Mn(CO)3).

  3. 3.

    Reaction of (CN)2C=C(Fc)CH2I with Cp(CO)2FeNa gave (CN)2C=C(Fc)CH3 and CP(CO)2FeI,

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    L. I. Leont'eva, Von Bek, D. N. Kravtsov & E. G. Perevalova

  2. M. V. Lomonosov Moscow State University, USSR

    L. I. Leont'eva, Von Bek, D. N. Kravtsov & E. G. Perevalova

Authors
  1. L. I. Leont'eva
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  2. Von Bek
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  3. D. N. Kravtsov
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  4. E. G. Perevalova
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Translated from Izvestiya Akademii Nauk SSSR, No. 10, pp. 2302–2307, October, 1986.

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Leont'eva, L.I., Bek, V., Kravtsov, D.N. et al. Reactions of 3,3-dicyano-2-ferrocenylallyl(cyclopentadienyl)dicarbonyliron with electrophilic and nucleophilic reagents. Russ Chem Bull 35, 2105–2110 (1986). https://doi.org/10.1007/BF00957534

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  • DOI: https://doi.org/10.1007/BF00957534

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