Conclusions
It has been established by the methods of x-ray diffraction analysis and electron diffraction analysis and measurements of the dipole moments and the birefringence that in the crystalline and gaseous phases, as well as in solution, N,N-dimethoxyamine has a gauche-gauche conformation, which is stipulated by a stabilizing nOπ-σN-O* orbital interaction. The geometric parameters of the molecule have been determined.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2235–2242, October, 1986.
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Antipin, M.Y., Struchkov, Y.T., Shishkov, I.F. et al. Structure of dimethoxyamine in the crystalline and gaseous phases and in solution. Russ Chem Bull 35, 2040–2046 (1986). https://doi.org/10.1007/BF00957519
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DOI: https://doi.org/10.1007/BF00957519