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Carbonyl derivatives of ferrocene, cymanthrene, and benzenechromium tricarbonyl in electrochemical syntheses

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    An electrochemical synthesis of acetylcymanthrene from 1,1′-diacetylferrocene and dimanganese decacarbonyl was carried out.

  2. 2.

    It was proposed that the electrochemical reduction of acetyl derivatives of ferrocene, cymanthrene, and benzenechromium tricarbonyl in CH3CN, leading to cyanoalkyl compounds, be used as a method for elongating the side chain of the above π-complexes by two C atoms.

  3. 3.

    It was shown that as in the case of ferrocene, the ferrocenyl radicals can be electrochemically alkylated.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    M. G. Peterleitner, L. I. Denisovich & D. N. Kravtsov

Authors
  1. M. G. Peterleitner
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  2. L. I. Denisovich
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  3. D. N. Kravtsov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 442–445, February, 1988.

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Peterleitner, M.G., Denisovich, L.I. & Kravtsov, D.N. Carbonyl derivatives of ferrocene, cymanthrene, and benzenechromium tricarbonyl in electrochemical syntheses. Russ Chem Bull 37, 361–364 (1988). https://doi.org/10.1007/BF00957446

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  • DOI: https://doi.org/10.1007/BF00957446

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