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1,3-Elimination in γ-halogen- and γ-ammonium-1-boraadamantane ate-complexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Complexes of 2-(2-halogenoidethyl)-1-boraadamantanes with tetrahydrofuran and pyridine have been synthesized by the hydroboration-isomerization of 3-methoxy-7-(3-halogenoidpropyl)-3-borabicyclo[3.3.1]non-6-enes.

  2. 2.

    4-Chloro-, and 2-(2-halogenoidethyl)-, and 2-(2-trimethylammoniumethyl)-1-boraadamantane ate-complexes undergo self-induced 1,3-elimination, resulting in the formation of substituted 3-borabicyclo[3.3.1]nonanes containing a cyclopropane fragment.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    M. E. Gurskii, T. V. Potapova, K. L. Cherkasova & Yu. N. Bubnov

Authors
  1. M. E. Gurskii
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  2. T. V. Potapova
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  3. K. L. Cherkasova
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  4. Yu. N. Bubnov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 415–420, February, 1988.

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Gurskii, M.E., Potapova, T.V., Cherkasova, K.L. et al. 1,3-Elimination in γ-halogen- and γ-ammonium-1-boraadamantane ate-complexes. Russ Chem Bull 37, 334–338 (1988). https://doi.org/10.1007/BF00957439

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  • DOI: https://doi.org/10.1007/BF00957439

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