Conclusions
Reactions of ketimines metallated with Grignard reagents with allyl N-, O-, and S-containing substrates are catalyzed by Pd complexes and result in α-substituted ketones.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 378–382, February, 1988.
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Dzhemilev, U.M., Minsker, D.L., Khalilov, L.M. et al. Synthesis of α-substituted ketones by reaction of metallated ketimines with allyl compounds under the action of palladium complexes. Russ Chem Bull 37, 298–302 (1988). https://doi.org/10.1007/BF00957430
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DOI: https://doi.org/10.1007/BF00957430