Conclusions
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1.
Two types of isomeric chelate compounds have been prepared in which deprotonated N-organyl-N′-(1,3-thiazol-2-yl)thiourea coordinates with R2B at the N atom of the thiazole ring and at the S or N atom of the thiocarbamide group (S- and N-isomers), the N-isomers being thermodynamically more stable than the S-isomers.
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2.
Complexes of diorganylboryl[2-(N-organyl)carbamoylaminothiazolates] (N-isomers) with Ni and Pd have been prepared.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2822–2825, December, 1987.
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Dorokhov, V.A., Boldyreva, O.G. & Bochkareva, M.N. Chelates of boron with N-organyl-N′-(1,3-thiazol-2-YL)thioureas and their use as ligands for complexes with transition metals. Russ Chem Bull 36, 2619–2622 (1987). https://doi.org/10.1007/BF00957248
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DOI: https://doi.org/10.1007/BF00957248