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Vibrational spectroscopic study of the structure of Ti(III) organometallic compounds

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A full interpretation was carried out for the vibrational spectra of TiR3, where R= -CH2C6H5, -CH2C(CH3)2C6H5, and-CH2Si(CH3)3. The absorption bands for the Ti-C bonds were delineated. A dimeric structure was established for the compounds studied with a Ti-Ti bond, whose band lies at 230–280 cm−1. There is an interaction of the titanium atom with the β-carbon atom of the ligand for the Ti(III) benzyl and neophyl derivatives.

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Literature cited

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Authors and Affiliations

  1. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    S. B. Sverchinskaya, G. N. Bondarenko, I. Sh. Guzman, E. I. Tinyakova & G. A. Dolgoplosk

Authors
  1. S. B. Sverchinskaya
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  2. G. N. Bondarenko
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  3. I. Sh. Guzman
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  4. E. I. Tinyakova
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  5. G. A. Dolgoplosk
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2736–2739, December, 1987.

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Sverchinskaya, S.B., Bondarenko, G.N., Guzman, I.S. et al. Vibrational spectroscopic study of the structure of Ti(III) organometallic compounds. Russ Chem Bull 36, 2536–2539 (1987). https://doi.org/10.1007/BF00957228

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  • DOI: https://doi.org/10.1007/BF00957228

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