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Iron carbonyl complexes containing the azomethylene fragment. 6. Interconversion of Fe2-μ-(o-C6H4CH2NC6H5)(CO)6 and Fe3-μ-(o-C6H4CH2NC6H5)(CO)8

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The binuclear complex Fe2-μ-(o-C6H4CH2NC6H5)(CO)6 and the trinuclear complex Fe3-μ-(o-C6H4CH2NC6H5)(CO)8 undergo interconversion by addition and cleavage of iron carbonyl moieties.

  2. 2.

    The arene ligand in Fe3-μ-(o-C6H4CH2NC6H5)(CO)8 is bonded by an exocyclic double bond to one of the iron atoms, and by five π-electrons to the Fe(CO)2 group.

  3. 3.

    Iron carbonyl fragments are readily cleaved from Fe3-μ-(o-C6H4CH2NC6H5)(CO)8 by treatment with sulfur or Fe2(CO)6S2.

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Literature cited

  1. N. S. Nametkin, V. D. Tyurin, A. I. Nekhaev, et al., J. Organomet. Chem.,243, 323 (1983).

    Google Scholar 

  2. N. S. Nametkin, V. D. Tyurin, V. V. Trusov, et al., J. Organomet. Chem.,276, 199 (1984).

    Google Scholar 

  3. N. A. Vol'kenau, Methods of Heteroorganic Chemistry. π-Complexes of Transition Metals with Dienes, Arenes, and Compounds with M-C o-bonds [in Russian], Moscow (1976), p. 129.

  4. T. V. Nikitina, Methods of Heteroorganic Chemistry. Organometallic Compounds of Iron [in Russian], Nauka, Moscow (1985), pp. 157–158.

    Google Scholar 

  5. A. C. Day and J. T. Powell, J. Chem. Soc. Chem. Commun., 1241 (1968).

  6. E. O. Fischer, W. Berngruber, and C. G. Kreiter, J. Organomet. Chem.,14, 25 (1968).

    Google Scholar 

  7. S. R. Weber and H. H. Brintzinger, J. Organomet. Chem.,127, 45 (1977).

    Google Scholar 

  8. G. G. Aleksandrov, Yu. P. Sobolev, A. I. Nekhaev, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2534 (1986).

  9. Yu. A. Borisov and I. I. Kritskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 576 (1984).

  10. Yu. V. Chizhov, M. M. Timoshenko, V. I. Kleimenov, et al., Zh. Strukt. Khim.,27, 69 (1986).

    Google Scholar 

  11. K. Ingold, The Theoretical Foundations of Organic Chemistry [Russian translation], Mir, Moscow (1973), p. 181.

    Google Scholar 

  12. A. Solladie-Cavallo, J. Suffert, and A. de Cian, J. Organomet. Chem.,236, 83 (1982).

    Google Scholar 

  13. V. V. Trusov, A. I. Nekhaev, Yu. V. Maksimov, and V. D. Tyurin, Izv. Akad. Nauk SSSR, Ser. Khim., 1903 (1985).

  14. J. A. S. Howell, B. F. G. Johnson, P. L. Josty, and J. Lewis, J. Organomet. Chem.,39, 329 (1972).

    Google Scholar 

  15. N. S. Nametkin, V. D. Tyurin, M. A. Kukina, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 2384 (1977).

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Authors and Affiliations

  1. A.V. Topichev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    A. I. Nekhaev, Yu. P. Sobolev & N. I. Dorokhina

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  1. A. I. Nekhaev
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  2. Yu. P. Sobolev
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  3. N. I. Dorokhina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1133–1136, May, 1988.

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Nekhaev, A.I., Sobolev, Y.P. & Dorokhina, N.I. Iron carbonyl complexes containing the azomethylene fragment. 6. Interconversion of Fe2-μ-(o-C6H4CH2NC6H5)(CO)6 and Fe3-μ-(o-C6H4CH2NC6H5)(CO)8 . Russ Chem Bull 37, 994–997 (1988). https://doi.org/10.1007/BF00957077

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  • DOI: https://doi.org/10.1007/BF00957077

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