Skip to main content
SpringerLink
Log in

Hydrogenolysis of propane on a palladium-ruthenium alloy membrane catalyst

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rate of hydrogenolysis of propane and the selectivity for methane in delivery of hydrogen through a Pd-Ru alloy membrane catalyst is lower than in conducting the reaction in conditions of combined delivery of hydrogen and propane.

  2. 2.

    In the 433–533 K temperature region corresponding to the coexistence of the α and β phases of palladium hydride, the rate of hydrogenolysis of propane does not increase with an increase in the temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. J. H. Sinfelt, Adv. Catal.,23, 91 (1973).

    Google Scholar 

  2. J. L. Carter, J. A. Cusumano, and J. H. Sinfelt, J. Catal.,20, 223 (1971).

    Google Scholar 

  3. M. F. Guillex, J. A. Dalmon, and G. A. Martin, J. Catal.,62, 235 (1980).

    Google Scholar 

  4. L. Guczi, A. Sarkany, and P. Tetenyi, J. Chem. Soc. Faraday Trans. 1,70, 1971 (1974).

    Google Scholar 

  5. A. B. Shekhter and I. I. Tret'yakov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, No. 3, 442 (1953).

    Google Scholar 

  6. A. P. Rudenko, Sovr. Prob. Fiz. Khim.,3, 263 (1968).

    Google Scholar 

  7. E. S. Shpiro, T. S. Ustinova, V. S. Smirnov et al., Izv. Akad. Nauk SSSR, Ser. Khim., 763 (1978).

  8. N. V. Orekhova, M. M. Ermilova, V. S. Smirnov, and V. M. Gryaznov, Izv. Akad. Nauk SSSR, Ser. Khim., 2602 (1976).

  9. P. Tetenyi, L. Guczi, and Z. Paal, Acta Chim.,83, 37 (1974).

    Google Scholar 

  10. W. D. Gillespie, R. K. Herz, E. E. Petersen, and G. A. Somorjai, J. Catal.,70, 147 (1981).

    Google Scholar 

  11. A. P. Mishchenko, Metals and Alloys as Membrane Catalysts [in Russian], Nauka, Moscow (1981), p. 56.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. P. Lumumba University, Moscow

    E. V. Skakunova, M. M. Ermilova & V. M. Gryaznov

  2. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    E. V. Skakunova, M. M. Ermilova & V. M. Gryaznov

Authors
  1. E. V. Skakunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. M. Ermilova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Gryaznov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 986–991, May, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Skakunova, E.V., Ermilova, M.M. & Gryaznov, V.M. Hydrogenolysis of propane on a palladium-ruthenium alloy membrane catalyst. Russ Chem Bull 37, 858–861 (1988). https://doi.org/10.1007/BF00957044

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00957044

Keywords

Search

Navigation