Summary
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1.
In the interaction of bicyclo[2.2.1]hepta-2, 5-diene with decationized and rare-earth zeolites (H-TsVM, H-Ultrasil, H-mordenite, NaNdY), including the dealuminized NdNaY', widepore aluminosilicates and filled zeolite (AShNTs), activated under conditions such that sorbed water remains in (or is added to) the catalyst, alcohols are formed — 3-hydroxynortricyclane and 3-dehydronorborneol — together with ethers — 3-(tricyclo[2.2.1.O2,6]-3′-heptyloxy)-bicyclo [2.2.1 ] hept-5-ene and 3,3′-oxydinortricyclane.
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With aromatic compounds in the presence of wide-pore REE-Y zeolites and also AShNTs, activated at 500°C, norbornadiene forms alkylated products such as endo-5-phenyl-2-norbornene from benzene.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1238–1242, June, 1986.
The authors wish to thank V. I. Tikhomirov for consultations on the analysis of the high-silica zeolites.
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Azbel', B.I., Gol'dshleger, N.F., Isakov, Y.I. et al. Reactions of bicyclo[2.2.1]hepta-2,5-diene in the presence of zeolites. Russ Chem Bull 35, 1122–1125 (1986). https://doi.org/10.1007/BF00956579
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DOI: https://doi.org/10.1007/BF00956579