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Epoxidation of the products of codimerization of cyclopentadiene and cyclohexadiene hydrocarbons catalyzed by lanthanide-molybdenum polyoxometalates

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Abstract

[4+2]-Codimerization of cyclohexa-1,3-diene, cyclopentadiene, and their methyl-substituted derivatives in the presence of H-forms of synthetic mordenite and natural clinoptilolite was studied. Application of zeolites as catalyst decreases the rate of di- and trimerization of cyclopentadiene and its methyl-substituted derivatives, increases the reaction selectivity with respect to their codimers with cyclohexa-1,3-diene and its methylsubstituted derivatives as well as 4-vinylcyclohexene. Epoxidation of the synthesized codimers with the adduct of hydrogen peroxide with urea in the presence of gadolinium- and neodymium-containing phosphorus molybdenum complexes as catalysts has been investigated, and optimal conditions for preparation of diepoxides of tricyclic dienes have been found.

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Authors and Affiliations

  1. Mamedaliev Institute of Petrochemical Processes, Azerbaijan National Academy of Sciences, pr. Khojaly 30, Baku, AZ1025, Azerbaijan

    N. I. Garibov, Kh. M. Alimardanov, N. R. Dadashova, O. A. Sadygov, M. B. Almardanova & A. D. Kuliev

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  1. N. I. Garibov
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  2. Kh. M. Alimardanov
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  3. N. R. Dadashova
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  4. O. A. Sadygov
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  5. M. B. Almardanova
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  6. A. D. Kuliev
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Correspondence to O. A. Sadygov.

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Original Russian Text © N.I. Garibov, Kh.M. Alimardanov, N.R. Dadashova, O.A. Sadygov, M.B. Almardanova, A.D. Kuliev, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 5, pp. 726–734.

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Garibov, N.I., Alimardanov, K.M., Dadashova, N.R. et al. Epoxidation of the products of codimerization of cyclopentadiene and cyclohexadiene hydrocarbons catalyzed by lanthanide-molybdenum polyoxometalates. Russ J Gen Chem 85, 1025–1033 (2015). https://doi.org/10.1134/S1070363215050035

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  • DOI: https://doi.org/10.1134/S1070363215050035

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