Skip to main content
SpringerLink
Log in

Redox reactions of mercury derivatives of 8-alkylquinolines with Pd(0) and Pt(0) complexes

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Redox demercuration of mercury derivatives of 8-alkylquinolines by Pd(0) and Pt(0) complexes affords 5-membered chelate metallocycles, except for the reaction between 8-(α-bromomercuriethyl)quinoline and (Ph3P)3Pt.

  2. 2.

    X-ray structural analysis of the triphenylphosphine-(8-methylquinoline-C,N)palladium bromide molecule has shown that the phosphine ligand is trans-oriented to the nitrogen atom in the Pd coordination sphere.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. V. Bashilov, V. I. Sokolov, and O. A. Reutov, Izv. Akad. Nauk SSSR, Ser. Khim., 2069 (1982).

  2. V. I. Sokolov and V. V. Bashilov, Zh. Org. Khim.,14, 1114 (1978).

    Google Scholar 

  3. O. A. Reutov, V. V. Bashilov, and V. I. Sokolov, Izv. Akad. Nauk SSSR, Ser. Khim., 1169 (1981).

  4. G. E. Hartwell, R. V. Lawrence, and M. J. Smas, J. Chem. Soc., Chem. Communs., 912 (1970).

  5. V. I. Sokolov, T. A. Sorokina, L. L. Troitskaya, L. I. Solovieva, and O. A. Reutov, J. Organomet. Chem.,36, 389 (1972).

    Google Scholar 

  6. A. R. Garber, P. E. Garrou, G. E. Hartwell, J. R. Wilkinson, and L. J. Todd, J. Organomet. Chem.,86, 219 (1975).

    Google Scholar 

  7. L. L. Troitskaya, A. I. Grandberg, V. I. Sokolov, and O. A. Reutov, Dokl. Akad. Nauk SSSR,228, 367 (1976).

    Google Scholar 

  8. V. I. Sokolov, Inorg. Chim. Acta,18, L9 (1976).

    Google Scholar 

  9. V. I. Sokolov, V. V. Bashilov, A. A. Musaev, and O. A. Reutov, J. Organomet. Chem.,225, 57 (1982).

    Google Scholar 

  10. K. S. Y. Lau, P. K. Wong, and J. K. Stille, J. Am. Chem. Soc.,98, 5832 (1976).

    Google Scholar 

  11. J. K. Stille and K. S. Y. Lau, Acc. Chem. Res.,10, 434 (1977).

    Google Scholar 

  12. V. I. Andrianov, Z. Sh. Safina, and B. L. Tarnopol'skii, An Automated Suite of Programs for the Interpretation of Crystal Structures [in Russian], Chernogolovka, Institute of Physical Chemistry of the Academy of Sciences of the USSR (1975).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    V. V. Bashilov, É. V. Maskaeva, A. A. Musaev, V. I. Sokolov & O. A. Reutov

Authors
  1. V. V. Bashilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. É. V. Maskaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Musaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. A. Reutov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1597–1601, July, 1984.

The authors thank L. L. Troitskaya, P. V. Petrovskii, and I. R. Amiraslanov for their assistance in this work.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bashilov, V.V., Maskaeva, É.V., Musaev, A.A. et al. Redox reactions of mercury derivatives of 8-alkylquinolines with Pd(0) and Pt(0) complexes. Russ Chem Bull 33, 1466–1470 (1984). https://doi.org/10.1007/BF00956528

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00956528

Keywords

Search

Navigation