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Investigation of the reaction of phenyl radicals with phenyl esters of thiocabboxylic acids

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Phenyl radicals add to the phenyl esters of thiocarboxylic acids

    (R=Ph, Ph2CH, PhCH2) at the sulfur atom of the C=S group with the formation of radical-adducts of the type

    , which were identified by ESR using a spin trap technique.

  2. 2.

    The radical-adduct Ph2

    is converted into the O,S-bis-phenylacetal of diphenylketene and the phenyl ester of diphenylthioacetic acid while the radical-adduct

    is converted into the phenyl ester of thiobenzoic acid and diphenyldisulfide.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    R. G. Petrova, R. G. Gasanov, T. D. Churkina, V. I. Dostovalova & R. Kh. Freidlina

Authors
  1. R. G. Petrova
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  2. R. G. Gasanov
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  3. T. D. Churkina
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  4. V. I. Dostovalova
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  5. R. Kh. Freidlina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, pp. 1576–1581, July, 1984.

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Petrova, R.G., Gasanov, R.G., Churkina, T.D. et al. Investigation of the reaction of phenyl radicals with phenyl esters of thiocabboxylic acids. Russ Chem Bull 33, 1447–1451 (1984). https://doi.org/10.1007/BF00956523

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  • DOI: https://doi.org/10.1007/BF00956523

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