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Synthesis of polysaccharides Communication 13. Synthesis of 1,3-glucan

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

We synthesized 1,2-O-exo-cyanoethylidene-4,6-di-O-acetyl-3-O-trityl-α-D-glucopyranose. The polycondensation of this product led to 1,3-glucan containing bothβ-D-glucopyranose andα-D-glucopyranose units in approximately equal ratio.

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Literature cited

  1. N. K. Kochetkov, Izv. Akad. Nauk SSSR, Ser. Khim., 1543 (1982).

  2. A. E. Clarke and B. A. Stone, Rev. Pure Appl. Chem.,13, 134 (1963).

    Google Scholar 

  3. N. K. Kochetkov and N. N. Malysheva, Izv. Akad. Nauk SSSR, Ser. Khim., 196 (1981).

  4. N. K. Kochetkov and N. N. Malysheva, Carbohydr. Res.,105, 173 (1982).

    Google Scholar 

  5. C. B. Reese and J. C. M. Stewart, Tetrahedron Lett., 4273 (1968).

  6. V. I. Betaneli, M. V. Ovchinnikov, L. V. Bakinovskii, and N. K. Kochetkov, Izv. Akad, Nauk SSSR, Ser. Khim., 2751 (1979).

  7. Ya. V. Vozney, L. V. Bakinovskii (Backinowsky), and N. K. Kochetkov, Carbohydr. Res.,73, 282 (1979).

    Google Scholar 

  8. N. K. Kochetkov and E. M. Klimov, Izv. Akad. Nauk SSSR, Ser. Khim., 200 (1981).

  9. P. Colson, H. J. Jennings.and I. C. P. Smith, J. Am. Chem. Soc.,96, 8081 (1974).

    PubMed  Google Scholar 

  10. N. K. Kochetkov, V. I. Betaneli, M. V. Ovchinnikov, and L. V. Bakinovskii (Backinowsky), Tetrahedron Lett.,37, Suppl. 9, 149 (1981).

    Google Scholar 

  11. A. F. Bochkov, I. V. Obruchnikov, V. M. Kalinevich, and N. K. Kochetkov, Bioorg. Khim.,2, 1085 (1976).

    Google Scholar 

  12. J. Zachoval and C. Schuerch, J. Am. Chem. Soc.,91, 1165 (1969).

    Google Scholar 

  13. J. Van Alphen, Rec. Trav. Chim.,46, 144 (1927).

    Google Scholar 

  14. H. Bredereck and G. Höschele, Chem. Ber.,86, 47 (1953).

    Google Scholar 

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Translated from Izevestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1170–1177, May, 1983.

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Kochetkov, N.K., Malysheva, N.N. & Klimov, E.M. Synthesis of polysaccharides Communication 13. Synthesis of 1,3-glucan. Russ Chem Bull 32, 1056–1061 (1983). https://doi.org/10.1007/BF00956168

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  • DOI: https://doi.org/10.1007/BF00956168

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