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Influence of radical center on oxidative properties of nitron group in reaction of nitroxyl radicals of 3-imidazoline 3-oxide withhydrazine

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The influence of the radical center on the reactivity of the functional group in derivatives of 3-imidazoline 3-oxide not bound directly to it has been discovered.

  2. 2.

    In the reaction of nitroxyl radicals of a series of 3-imidazoline 3-oxides with hydrazine, two parallel processes take place: Reduction of the radical center to a hydroxylamino group and reduction of the nitron group to an amino group.

  3. 3.

    The desoxygenation process of the nitron group by hydrazine in alcohol at 20°C proceeds in the case of paramagnetic derivatives of 3-imidazoline 3-oxide only.

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Authors and Affiliations

  1. Novosibirsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    I. A. Grigor'ev, G. I. Shchukin & L. B. Volodarskii

Authors
  1. I. A. Grigor'ev
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  2. G. I. Shchukin
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  3. L. B. Volodarskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1140–1146, May, 1983.

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Grigor'ev, I.A., Shchukin, G.I. & Volodarskii, L.B. Influence of radical center on oxidative properties of nitron group in reaction of nitroxyl radicals of 3-imidazoline 3-oxide withhydrazine. Russ Chem Bull 32, 1030–1035 (1983). https://doi.org/10.1007/BF00956162

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  • DOI: https://doi.org/10.1007/BF00956162

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