Skip to main content
SpringerLink
Log in

Relation of the gas chromatographic retention indexes of isomeric alkylcyclohexenoate esters to their structure and conformation

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Retention indexes have been determined for 29 methyl esters of alkyl-substituted cyclohexanoic and cyclohexenoic acids on capillary columns with polar stationary phases.

  2. 2.

    The cyclohexenoate and cyclohexanoate esters with methyl substituents at position 2 may exist in a stable conformation with an axial carbomethoxy group; this permits gas chromatography to be used to ascertain the stable conformations of cyclohexane and cyclohexene derivatives.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. F. Kucherov, A. S. Onishchenko, B. A. Rudenko, and E. A. Él'perina, Dokl Akad. Nauk SSSR,158, 397 (1964).

    Google Scholar 

  2. B. A. Rudenko, S. Ya. Metlyaeva, and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 1224 (1970).

  3. B. A. Rudenko, S. Ya. Metlyaeva, and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 2126, 2500 (1972).

    Google Scholar 

  4. B. A. Rudenko, S. Ya. Metlyaeva, and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 1275 (1973).

  5. B. S. Él'yanov, B. A. Rudenko, M. G. Gonikberg, and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 1082 (1964).

  6. C. Baron and B. Maume, Bull. Soc. Chim. France, 1113 (1962).

  7. R. Komers and K. Kochloefl, Collect. Czech. Chem. Commun.,28, 46 (1963).

    Google Scholar 

  8. V. M. Potapov, Stereochemistry [in Russian], Khimiya, Moscow (1976).

    Google Scholar 

  9. Gas Chromatography. A Bibliographic Index to Domestic and Foreign Literature [in Russian], Nauka, Moscow (1962–1977), Vols. 1–4.

  10. V. N. Paukov, and B. A. Rudenko, Zavod. Lab.,34, 155 (1968).

    Google Scholar 

  11. V. N. Paukov, B. A. Rudenko, and V. F. Kucherov, Zh. Anal. Khim.,23, 1247 (1968).

    Google Scholar 

  12. V. N. Paukov, B. A. Rudenko, and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 15 (1968).

  13. A. P. Znamenskaya and L. I. Anan'eva, in: Gas Chromatography [in Russian], Nauka, Moscow (1964), p. 240.

    Google Scholar 

  14. L. S. Leshchiner, L. M. Ugarova, and B. A. Rudenko, in: Advances in Gas Chromatography [in Russian], No. 19, NIITÉKhim, Moscow (1973).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    B. A. Rudenko

Authors
  1. B. A. Rudenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk USSR, Seriya Khimicheskaya, No. 5, pp. 1108–1112, May, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rudenko, B.A. Relation of the gas chromatographic retention indexes of isomeric alkylcyclohexenoate esters to their structure and conformation. Russ Chem Bull 32, 1002–1005 (1983). https://doi.org/10.1007/BF00956154

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00956154

Keywords

Search

Navigation