Summary
Several cobalt(II) halide complexes derived from 1,8-bis(2-pyridyl)-3,6-dithiaoctane (bpdto) are described. Chemical analysis suggests their formulae to be: Co(bpdto)X2 (X=Cl−, Br−, or I−). Electrolytic conductivities in acetonitrile, magnetic moments at different temperatures, solid state i.r. and u.v.-visible spectra support a tetrahedral stereochemistry around the cobalt(II). The ligand is bidentate andN-bonded in all cases.
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This work was presented in the Fifth Annual Meeting of the Portuguese Chemical Society, Porto (Portugal), March 1982.
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Castiñeiras, A., Molleda, C., Masaguer, J.R. et al. Complexes of 1,8-bis(2-pyridyl)-3,6-dithiaoctane with cobalt(II) halides. Transition Met Chem 8, 129–131 (1983). https://doi.org/10.1007/BF00956017
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DOI: https://doi.org/10.1007/BF00956017