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Synthesis and properties of (η5-cyclopentadienyl)-(η2-2-propyn-1-ol)dicarbonylmanganese

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A new π-complex of 2-propyn-1-ol with cyclopentadienyldicarbonylmanganese CpMn(CO)2(π-HC≡ CCH2OH) (I) was obtained by photochemical reaction of cymantrene, and also by the exchange reaction between CpMn(CO)2(THF) and 2-propyn-1-ol.

  2. 2.

    The action of bases and protic acids on (I) leads to a rearrangement of the π-acetylene ligand to form a new p-vinylidene complex CpMn(CO)2=C =CHCH2OH.

  3. 3.

    The reaction between (I) and PPh3 leads to an addition product with the formation of a new complex CpMn(CO)2(C3H4O)·PPh3.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    N. E. Kolobova, L. L. Ivanov, Yu. A. Chernykh & V. V. Derunov

Authors
  1. N. E. Kolobova
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  2. L. L. Ivanov
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  3. Yu. A. Chernykh
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  4. V. V. Derunov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1395–1399, June, 1982.

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Kolobova, N.E., Ivanov, L.L., Chernykh, Y.A. et al. Synthesis and properties of (η5-cyclopentadienyl)-(η2-2-propyn-1-ol)dicarbonylmanganese. Russ Chem Bull 31, 1243–1246 (1982). https://doi.org/10.1007/BF00955989

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  • DOI: https://doi.org/10.1007/BF00955989

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