Skip to main content
Log in

Molecular and crystal structure of 4,6-dimethyl-2,6-diphenyl-1-phospha-2,3-diazabicyclo[3.1.0] hex-3-ene

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

An x-ray diffraction structural analysis gave the structure of 4,6-dimethyl-2,6-diphenyl-1-phospha-2,3-diazabicyclo[3.1.0]hex-3-ene (III). Short intermolecular P...P contacts of 3.483 Å are found in the crystal of this compound due to distortion of the van der Waals radius of the phosphorus atom.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. B. A. Arbuzov and É. N. Dianova, Izv. Akad. Nauk SSSR, Ser. Khim., 1453 (1977).

  2. V. A. Arbuzov, V. D. Cherepinskii-Malov, É. N. Dianova, A. I. Gusev, and V. A. Sharapov, Dokl. Akad. Nauk SSSR,243, 358 (1978).

    Google Scholar 

  3. T. J. Katz, C. R. Nicolson, and C. A. Reilly, J. Am. Chem. Soc.,88, 3832 (1966).

    Google Scholar 

  4. H. L. Amman, P. H. Marrocchi, M. C. Regan, and E. Colicelli, Acta Crystallogr.,35, 1722 (1979).

    Google Scholar 

  5. E. Bayer and G. Hafelinger, Chem. Ber.,99, 1189 (1966).

    Google Scholar 

  6. V. G. Andrianov, Yu. T. Struchkov, N. I. Shvetsov-Shilovskii, N. B. Ignatova, R. T. Bobkova, and N. N. Mel'nikov, Dokl. Akad. Nauk SSSR,211, 1101 (1973).

    Google Scholar 

  7. S. C. Nyburg, Acta Crystallogr.,30, 251 (1974).

    Google Scholar 

  8. P. M. Zorkii and A. E. Razumaeva, Zh. Strukt. Khim.,20, 463 (1979).

    Google Scholar 

  9. L. Pauling, The Nature of the Chemical Bond, Cornell University Press, New York-Ithaca (1960).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2275–2279, October, 1983.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Litvinov, I.A., Struchkov, Y.T., Arbuzov, B.A. et al. Molecular and crystal structure of 4,6-dimethyl-2,6-diphenyl-1-phospha-2,3-diazabicyclo[3.1.0] hex-3-ene. Russ Chem Bull 32, 2053–2057 (1983). https://doi.org/10.1007/BF00955770

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00955770

Keywords

Navigation