Conclusions
During photolysis of p-ethynyl-N,N-dimethylaniline in CCl4, products are formed that are exclusively due to a reaction at the triple bond and amino group, without affecting the aromatic ring: p-dimethylaminoacetophenone, N-methyl-N-(p-ethynylphenyl)-carbamoyl chloride, N-methyl-N-[p-(α-chlorovinylphenyl)]-carbamoyl chloride, p-dimethylamino-α-chlorostyrene, and p-dimethylamino-α,β-dichlorostyrene.
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M. I. Bardamova, I. L. Kotlyarevskii, and Z. P. Trotsenko, Izv. Akad. Nauk SSSR, Ser. Khim., 1184 (1982); 407 (1984); 821 (1984).
L. A. Blyumenfel'd, V. V. Voevodskii, and A. G. Semenov, Use of Electronic Paramagnetic Resonance in Chemistry [in Russian], Izd. Sib. Otd. Akad. Nauk SSSR, Novosibirsk (1962), p. 220.
R. M. Silverstein, G. C. Bassler, and T. C. Morrill, Spectrometric Identification of Organic Compounds, Wiley, New York (1974).
T. Z. Latowski, Z. Naturforsch.,23a, 1127 (1968).
T. Latowski, E. Latowska, B. Poplawska, M. Przytarska, M. Waleczak, and B. Zelent, Rocz. Chem.,54, 1073 (1980).
J. G. Grasselli (ed.), Atlas of Spectral Data and Physical Constants for Organic Compounds, CRS Press, Cleveland (1973), p. B-129.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1163–1166, May, 1986.
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Usov, O.M., Bardamova, M.I. & Kotlyarevskii, I.L. Photochemistry of acetylenic derivatives of aromatic amines. Communication 1. Photolysis products of P-ethynyl-N,N-dimethylaniline in carbon tetrachloride. Russ Chem Bull 35, 1055–1057 (1986). https://doi.org/10.1007/BF00955380
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DOI: https://doi.org/10.1007/BF00955380