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Behavior of organic peroxides under conditions of high pressures and shear deformations

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The deformation process of decomposition of peroxides fundamentally differs from the thermal decomposition of peroxides in the solid phase and in solutions both at atmospheric and at high pressure.

  2. 2.

    The basic features of the chemical decomposition of the peroxides with shear deformation under high pressure are: the high rate, dependence of the degree of transformation on the value of the deformation, low-temperature coefficient, and different composition of the products of decomposition than in thermal decomposition of the peroxides in the solid phase and in solutions under atmospheric and high pressures.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

    A. I. Dyatlov, A. A. Zharov & V. M. Zhulin

Authors
  1. A. I. Dyatlov
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  2. A. A. Zharov
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  3. V. M. Zhulin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1028–1031, May, 1986.

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Dyatlov, A.I., Zharov, A.A. & Zhulin, V.M. Behavior of organic peroxides under conditions of high pressures and shear deformations. Russ Chem Bull 35, 932–935 (1986). https://doi.org/10.1007/BF00955352

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  • DOI: https://doi.org/10.1007/BF00955352

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