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Determination of the number of active sites of palladium-containing hydrogenation catalysts by batched introduction of carbon monoxide as inhibitor

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Using a method of batched introduction of carbon monoxide as inhibitor, determination was made of the upper limit of the relative number of active sites of palladium-containing catalysts for hydrogenation of unsaturated compounds.

  2. 2.

    For a homogeneous catalyst which was a complex of palladium chloride for trinonylamine and for one deposited on mineral supports, the number of active sites (for the unsaturated compounds investigated) constituted 5–12%, of the total quantity of palladium in the system.

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Authors and Affiliations

  1. A. P. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of the USSR, Moscow

    A. V. Novikova, A. I. Él'natanova, O. P. Parenago & V. M. Frolov

Authors
  1. A. V. Novikova
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  2. A. I. Él'natanova
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  3. O. P. Parenago
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  4. V. M. Frolov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 993–996, May, 1986.

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Novikova, A.V., Él'natanova, A.I., Parenago, O.P. et al. Determination of the number of active sites of palladium-containing hydrogenation catalysts by batched introduction of carbon monoxide as inhibitor. Russ Chem Bull 35, 901–904 (1986). https://doi.org/10.1007/BF00955345

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  • DOI: https://doi.org/10.1007/BF00955345

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