Conclusions
Allyl cations stabilized by the η5-C5H5-3-FeII-η5-1,2-C2B9H10-1 group, obtained for the first time in the pure state, display dual reactivity towards addition of the hydride ion.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
W. E. Watts, Organometallic Chem. Library,7, 399 (1979).
M. J. A. Habib, J. Park, and W. E. Watts, J. Chem. Soc., C, 2557 (1970).
L. I. Zakharkin and V. V. Kobak, Izv. Akad. Nauk SSSR, Ser. Khim., 2671 (1980).
L. I. Zarkharkin, V. V. Kobak, A. I. Yanovsky (Yanovskii), and Yu. T. Struchkov, Proceedings of the Tenth International Conference of Organometallic Chemistry, Toronto, Canada (1981), p. 173.
L. I. Zakharkin and V. V. Kobak, Izv. Akad. Nauk SSSR, Ser. Khim., 1919 (1982).
L. I. Zakharkin and V. V. Kobak, 2nd All-Union Conference of Organometallic Chemistry, Abstracts of Papers [in Russian], Gor'kii (1982), p. 247.
L. I. Zakharkin, V. V. Kobak, A. I. Yanovsky (Yanovskii), and Yu. T. Struchkov, Tetrahedron,38, 3515 (1982).
G. A. Olah and R. J. Spear, J. Am. Chem. Soc.,97, 539 (1975).
L. I. Zakharkin, V. V. Kobak, A. I. Yanovsky (Yanovskii) and Yu. T. Struchkov, J. Organomet. Chem.,228, 119 (1982).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2809–2814, December, 1983.
The authors thank P. V. Petrovskii for his help in obtaining and discussing the PMR spectra.
Rights and permissions
About this article
Cite this article
Zakharkin, L.I., Kobak, V.V. & Antonovich, V.A. Preparation of free stabilized allyl cations, stabilized by the η5-C5H5-3-FGIII-η5-1,2-C2B9¯H10-1 group. Russ Chem Bull 32, 2521–2526 (1983). https://doi.org/10.1007/BF00954486
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00954486